Page 34 - Kutnar, Andreja, et al., eds., 2015. Proceedings of the 1st COST Action FP1307 International Conference - Life Cycle Assessment, EPDs, and modified wood. University of Primorska Press, Koper.
P. 34
e
 cycle
 assessment
 of
 a
 novel
 tannin-­‐boron
 association
 for
 wood
 

protection
 

Jin-­‐Bo
 HU1,2,
 Campbell
 Skinner3,
 Graham
 Ormondroyd3,
 Gianluca
 Tondi4,
 Antonio
 Pizzi5,
 
 
Marie-­‐France
 Thevenon1
 

1
 Research
 Unit
 BIOWooEB,
 CIRAD,
 TA/B
 114/16,
 34398
 Montpellier
 Cedex
 5,
 France
 
2
 College
 of
 Material
 Science
 and
 Engineering,
 Central
 South
 University
 of
 Forestry
 and
 
Technology,
 Shaoshan
 South
 Road,
 No.
 498,
 Changsha,
 Hunan,
 410004,
 China
 
3
 BioComposites
 Centre,
 Bangor
 University,
 Bangor,
 Gwynedd,
 Wales
 LL57
 2UW,
 UK
 
4
 Forest
 Product
 Technology
 &
 Timber
 Construction
 Department,
 Salzburg
 University
 of
 
Applied
 Sciences,
 Marktstraße
 136a,
 Kuchl,
 5431,
 Austria
 
5
 LERMAB,
 University
 of
 Lorraine,
 27
 rue
 Philippe
 Séguin,
 CS
 60036,
 88026
 Epinal
 Cedex
 9,
 
France
 


 

Keywords:
  LCA,
  Tannin-­‐boron
  preservative,
  Landscaping
  materials,
  Treated
  timber,
  Low-­‐
environmental
 impact
 


 

Boron
 compounds
 remain
 in
 the
 wood
 preservation
 field
 and
 present
 many
 advantages.
 They
 are
 
also
  readily
  leachable
  from
  modified
  wood
  and
  several
  methods
  have
  been
  studied
  to
  fix
  boron
 
compounds
  for
  use
  in
  outdoor
  exposures
  (Obanda
  et
  al.
  2008).
  Of
  these
  studies,
  associations
 
between
  tannins
  and
  boron
  (TB)
  in
  the
  form
  of
  boric
  acid
  appear
  to
  be
  of
  interest.
  These
  TB
 
associations
  allow
  the
  use
  of
  boron
  at
  very
  low
  levels
  (in
  compliance
  with
  EU
  restrictions,
 
2008/58/EC)
  and
  limit
  boron
  leaching
  which
  maintains
  biological
  resistance
  and
  fire
  retardant
 
properties
  (Thevenon
  et
  al.
  2009,
  Tondi
  et
  al.
  2012).
  As
  a
  consequence,
  TB
  wooden
  products
 
present
  an
  extended
  service
  life
  compared
  to
  boron
  compounds
  alone
  and
  were
  designed
  to
  be
 
environmentally-­‐friendly
  wood
  protection
  systems.
  Until
  now
  the
  TB
  products
  have
  been
 
evaluated
 from
 a
 technical
 point
 of
 view
 and
 not
 for
 their
 potential
 environmental
 impact.
 
 

LCA’s
  were
  performed
  on
  tannin-­‐boron
  preservative
  products
  as
  well
  as
  several
  industrial
 
preservative-­‐treated
  timbers
  and
  concrete
  used
  in
  landscaping.
  Cr-­‐containing
  inorganic
  salt
  and
 
an
  alkaline
  copper
  quaternary
  preservative
  formulation,
  as
  well
  as
  concrete,
  have
  been
  used
  as
 
referential
  materials
  to
  compare
  the
  environmental
  footprint
  with
  the
  tannin-­‐boron
  treated
 
system.
  A
  model
  was
  created
  with
  life
  cycle
  stages
  used
  to
  calculate
  inputs
  and
  outputs
  during
 
raw
  material
  extraction,
  supplier
  transportation,
  manufacturing
  process,
  distribution,
  disposal
 
transportation
  and
  processing.
  Tannin
  production
  data
  were
  based
  on
  Vieira
  et
  al.
  (2011).
 
However,
 the
 extracted
 tannin
 in
 the
 extraction
 yield,
 the
 inorganic
 salt,
 and
 the
 process
 applied
 
are
  not
  perfectly
  comparable
  with
  the
  extraction
  conditions
  industrially
  applied
  to
  Mimosa
 
(Acacia
  mearnsii)
  extract
  which
  is
  the
  major
  constituent
  of
  the
  TB
  formulations.
  The
  latter
  is
 


  22
 
   29   30   31   32   33   34   35   36   37   38   39